Mysterio
Mysterio made his comic book debut in The Amazing Spider-Man # 13 in June of 1964.
Mysterio started out as Quentin Beck who worked as a special effects wizard and stunt man in Hollywood. He quickly saw he wasn't getting anywhere in his career and wanted to really make a name for himself.
His friend suggested that if he really wanted to become famous he should kill a superhero. So he chose Spiderman and started using his special effects and illusions to try and take him out.
Mysterio had an alias of a world-renowned psychiatrist named Dr. Ludwig Rhinehart who was working to convince Spiderman that he had gone crazy.
Below we have the best Mysterio memorabillia from eBay.